| Autor: |
Marc Würde, Bernd Speiser, M.G. Quintanilla |
| Rok vydání: |
2000 |
| Předmět: |
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| Zdroj: |
Electrochemistry Communications, Vol 2, Iss 1, Pp 65-68 (2000) |
| ISSN: |
1388-2481 |
| DOI: |
10.1016/s1388-2481(99)00141-1 |
| Popis: |
Hexakis(dimethylamino)benzene is electrochemically oxidized to species with oxidation states higher than that of a tetracation. The reaction is followed by cyclic voltammetry. A mechanistic scheme of the electrode reaction mechanism is proposed. Computer simulations of cyclic voltammograms at scan rates between 0.02 and 50 V s−1 allow the estimation of reaction parameters. A comparison of the potentials for the redox steps with data by other authors supports a re-interpretation of their results. Keywords: Anodic oxidation, Highly charged molecules, Polyaminobenzenes, Cyclic voltammetry, Computer simulation |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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Full Text from ScienceDirect