XAS on Rh and Ir metal sites in post synthetically functionalized UiO-67 Zirconium MOFs
| Autor: | Luca Braglia, Sigurd Øien, Kirill A. Lomachenko, Elisa Borfecchia, Carlo Lamberti, Karl Petter Lillerud |
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| Rok vydání: | 2016 |
| Předmět: |
History
Materials science Inorganic chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Education Rhodium Metal EXAFs Transition metal Ir Rh Iridium MOF Group 2 organometallic chemistry X-ray absorption spectroscopy Zirconium metallorganic framework Extended X-ray absorption fine structure 021001 nanoscience & nanotechnology XANES 0104 chemical sciences Computer Science Applications UiO-67 chemistry MOF metallorganic framework functionalization EXAFs XANES Rh Ir visual_art visual_art.visual_art_medium functionalization 0210 nano-technology |
| Zdroj: | 'Journal of Physics : Conference Series ', vol: 712, pages: 012053-1-012053-5 (2016) |
| ISSN: | 1742-6596 1742-6588 |
| DOI: | 10.1088/1742-6596/712/1/012053 |
| Popis: | We synthesized UiO-67 metal-organic-frameworks (MOFs) functionalized with different transition metals (Rh, Ir). Using EXAFS we verified that the synthesis has been successful. Furthermore, we observed the change of local environment while varying of metal site. XAS spectroscopy is the most informative technique to characterize these kind of materials and to study the local environment around the metal site. |
| Databáze: | OpenAIRE |
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