Synthesis of Cycloparaphenylenes Bearing Furan-2,5-diyl or 2,2'-Bifuran-5,5'-diyl Units in the Macrocyclic Structures

Autor:	Novruz G. Akhmedov, Shuangjiang Li, Jeffrey L. Petersen, Behzad Farajidizaji, Changfeng Huang, Notashia N. Baughman, Haresh Thakellapalli, Kung K. Wang, Brian V. Popp
Rok vydání:	2016
Předmět:	Bearing (mechanical) 010405 organic chemistry Chemistry Organic Chemistry Aromatization General Chemistry Crystal structure 010402 general chemistry Electrochemistry 01 natural sciences Combinatorial chemistry Catalysis Cycloaddition 0104 chemical sciences law.invention chemistry.chemical_compound law Furan Organic chemistry
Zdroj:	Chemistry (Weinheim an der Bergstrasse, Germany). 22(46)
ISSN:	1521-3765
Popis:	Synthetic pathways to furan-containing cycloparaphenylenes (CPPs) as molecular nanohoops bearing 10, 12, and 15 aromatic units including furan-2,5-diyl or 2,2′-bifuran-5,5′-diyl units have been developed. A [4 + 2]cycloaddition reaction, homo- or cross-coupling reactions, and an oxidative aromatization reaction are the key steps of the synthetic pathways. The X-ray structures of a partially hydrogenated bifuran-containing CPP precursor and the corresponding fully aromatized bifuran-containing CPP were obtained to allow the determination of their conformational arrangements in the crystal lattice. The optical and electrochemical properties of the furan-containing CPPs were investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9b483205c140d6f369a436521b0437c1 https://pubmed.ncbi.nlm.nih.gov/27607838 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.