Photonic shape memory polymer with stable multiple colors
Autor: | Monali Moirangthem, Jeffrey N. Murphy, Tap Tom Engels, Cwm Cees Bastiaansen, Aphj Albert Schenning |
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Přispěvatelé: | Stimuli-responsive Funct. Materials & Dev., Processing and Performance, Institute for Complex Molecular Systems |
Jazyk: | angličtina |
Rok vydání: | 2017 |
Předmět: |
Materials science
02 engineering and technology 010402 general chemistry mechanical embossing 01 natural sciences chemistry.chemical_compound Optics stable colors General Materials Science chemistry.chemical_classification Acrylate business.industry cholesteric liquid crystals semi-interpenetrating polymer network shape memory polymers Polymer Atmospheric temperature range 021001 nanoscience & nanotechnology 0104 chemical sciences Condensed Matter::Soft Condensed Matter Shape-memory polymer chemistry Optoelectronics Photonics 0210 nano-technology business Glass transition Embossing Structural coloration Research Article |
Zdroj: | ACS Applied Materials & Interfaces, 9(37), 32161-32167. American Chemical Society ACS Applied Materials & Interfaces |
ISSN: | 1944-8244 |
Popis: | A photonic shape memory polymer film that shows large color response (∼155 nm) in a wide temperature range has been fabricated from a semi-interpenetrating network of a cholesteric polymer and poly(benzyl acrylate). The large color response is achieved by mechanical embossing of the photonic film above its broad glass transition temperature. The embossed film, as it recovers to its original shape on heating through the broad thermal transition, exhibits multiple structural colors ranging from blue to orange. The relaxation behavior of the embossed film can be fully described using a Kelvin-Voigt model, which reveals that the influence of temperature on the generation of colors is much stronger than that of time, thereby producing stable multiple colors. |
Databáze: | OpenAIRE |
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