Azatriquinanes: Synthesis, Structure, and Reactivity

Autor:	David E. Hibbs, Oleg V. Shishkin, Mark Mascal, Alexander J. Blake, Michael B. Hursthouse, J. Hansen, Nicholas M. Hext
Rok vydání:	1998
Předmět:	chemistry.chemical_compound Chemistry Stereochemistry Organic Chemistry Polymer chemistry Chlorine chemistry.chemical_element Amine gas treating Reactivity (chemistry) Topology (chemistry) Pyrrole
Zdroj:	The Journal of Organic Chemistry. 63:6016-6020
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo980788s
Popis:	Azatriquinane, a tricyclic amine with rigid, hemispherical topology, is synthesized in six steps from pyrrole. This first example of a [2.2.2]cyclazine can be oxidatively dimerized to a novel, highly strained heptacycle or oxidized with chlorine to give an azatriquinacene, a theoretical precursor to diazadodecahedrane via Woodward dimerization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9ab13b19b9d8f952f90b60526ffe5090 https://doi.org/10.1021/jo980788s Zobrazit plný text záznamu