Norbornene based-sulfide-stabilized silylium ions: synthesis, structure and application in catalysis
| Autor: | Dajnak, Aymeric, Özpinar, Gül Altinbaş, Lenk, Romaric, Saffon-Merceron, Nathalie, Baceiredo, Antoine, Kato, Tsuyoshi, Müller, Thomas, Maerten, Eddy, Özpinar, Gül |
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| Přispěvatelé: | Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA), Institut de Chimie de Toulouse (ICT), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS), ANR-16-CE07-0018,WISSI,Interactions Faibles dans les Ions Silylium Stabilisés(2016) |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Dalton Transactions Dalton Transactions, 2022, 51 (4), pp.1407-1414. ⟨10.1039/d1dt04009j⟩ |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/d1dt04009j⟩ |
| Popis: | A norbornene-based sulfide stabilized silylium ion 4 has been synthesized. The S-Si interaction was studied in solution and in the solid state by NMR spectroscopy and X-ray diffraction analysis as well as DFT calculations. Unlike the previously reported phosphine-stabilized silylium ion VII, behaving as a Lewis pair, calculations predict that 4 should behave as a Lewis acid toward acrylate derivatives. Indeed, the base-stabilized silylium ion 4 has emerged as an easy-to-handle silylium ion-based Lewis acid catalyst, particularly for the Diels-Alder cycloaddition, with poorly reactive dienes, and hydrodefluorination reactions. |
| Databáze: | OpenAIRE |
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