New Procedure for the Synthesis of (Fulvalene)ditungsten Carbonyl Halides and Cyclopentadienyltungsten Carbonyl Halide Complexes with P-Donor Nucleophiles

Autor:	Consuelo Moreno, Rosa-María Medina, M.J. Macazaga, David H. Farrar, Salomé Delgado
Rok vydání:	1998
Předmět:	Inorganic Chemistry chemistry.chemical_compound Fulvalene Nucleophile chemistry Yield (chemistry) Organic Chemistry Organic chemistry Halide Physical and Theoretical Chemistry Medicinal chemistry Phosphine Cis–trans isomerism
Zdroj:	Scopus-Elsevier
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om980180+
Popis:	The reactions of (η5:η5-C10H8)W2(CO)6I2 and (η5-C5H5)W(CO)3I with P-donor nucleophiles (L = P(OMe)3, PPhMe2, P(n-Bu)3, PPh2Me, P(p-tol)3, P(m-tol)3, and PCy3) in the presence of 2 and 1 equiv, respectively, of Me3NO yield (η5:η5-C10H8)W2(CO)4L2I2 and (η5-C5H5)W(CO)2LI, respectively, as a mixture of cis/trans isomers. The relative proportion of these isomers is dependent of the stereoelectronic properties of the phosphine ligands. The X-ray structure of (η5:η5-(C10H8)W2(CO)6I2 has been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a1e7fcb7d9f59ac5936583bb8f3d00c https://doi.org/10.1021/om980180+ Zobrazit plný text záznamu