Potential Role of the Nitroacidium Ion on HONO Emissions from the Snowpack

Autor:	John R. Sodeau, Tristan B. Roddis, Stig Hellebust
Rok vydání:	2007
Předmět:	Dinitrogen tetroxide Dimer Photodissociation Inorganic chemistry Snowpack Photochemistry Ion chemistry.chemical_compound symbols.namesake Fourier transform chemistry symbols Nitrogen dioxide Physical and Theoretical Chemistry Thin film
Zdroj:	The Journal of Physical Chemistry A. 111:1167-1171
ISSN:	1520-5215 1089-5639
DOI:	10.1021/jp068264g
Popis:	The effects of photolysis on frozen, thin films of water-ice containing nitrogen dioxide (as its dimer dinitrogen tetroxide) have been investigated using a combination of Fourier transform reflection-absorption infrared (FT-RAIR) spectroscopy and mass spectrometry. The release of HONO is ascribed to a mechanism in which nitrosonium nitrate (NO+NO3-) is formed. Subsequent solvation of the cation leads to the nitroacidium ion, H2ONO+, i.e., protonated nitrous acid. The pathway proposed explains why the field measurement of HONO at different polar sites is often contradictory.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a0af2fea140db912ae90a28db8c9d1c https://doi.org/10.1021/jp068264g Zobrazit plný text záznamu