C−H Activation of Ethers and Alkanes by Germylene−Aryl Halide Complexes

Autor:	Jeff W. Kampf, Ryan D. Sweeder, Jeffrey M. Bartolin, Mark M. Banaszak Holl, Norman J. Wells, Karla A. Miller, Thomas M. Owens, Rory M. O'Neill
Rok vydání:	2003
Předmět:	Alkane chemistry.chemical_classification Aryl Aryl halide Halide Regioselectivity Ether General Chemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Organic chemistry
Zdroj:	Journal of the American Chemical Society. 125:8986-8987
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja0357285
Popis:	Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe3)2]2 and Ge[N(SiMe3)2]2, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a047a5259930a9619d8054ea9cf50ab https://doi.org/10.1021/ja0357285 Zobrazit plný text záznamu