Enhancing the sugars production yieldby supporting H3PW12O40 heteropoly acid on activated carbon for use as catalyst in hydrolysis of cellulose
| Autor: | Maria Lucia Bianchi, Ana Carolina Cunha Arantes, Saulo A. Carminati, Anna Cláudia Santos de Oliveira |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Heteropoly acid
Chemistry General Physics and Astronomy 02 engineering and technology General Chemistry Cellulose hydrolysis heteropoly acid Raw material 010402 general chemistry 021001 nanoscience & nanotechnology activated carbon support 01 natural sciences 0104 chemical sciences Catalysis Hydrolysis chemistry.chemical_compound Biofuel medicine hydrolysis of cellulose Organic chemistry General Materials Science Cellulose 0210 nano-technology Activated carbon medicine.drug |
| Zdroj: | Matéria (Rio de Janeiro) v.23 n.4 2018 Matéria (Rio de Janeiro. Online) instacron:RLAM Matéria (Rio de Janeiro), Volume: 23, Issue: 4, Article number: e12260, Published: 06 DEC 2018 |
| Popis: | In this work, two catalysts were produced to be used in hydrolysis of cellulose reactions to obtain glucose, a raw material used in the production of bioethanol. The heteropoly acid, H3PW12O40 (HPW), reported as strong and thermally stable acid, was supported on activated carbon (AC) in a ratio varying from 1:1 to 2:1 to produce the catalysts AC-HPW (1:1) and AC-HPW (2:1). The catalysts were tested in cellulose hydrolysis evaluating some reaction variables and the results show the remarkable dependence of reaction temperature, amount and acidity of the catalyst. The results indicate the advantage of supporting HPW on carbonaceous material for using as catalyst in hydrolysis of cellulose, showing better conversion rate into sugars comparing with unsupported HPW. Keywords: heteropoly acid; activated carbon support; hydrolysis of cellulose. |
| Databáze: | OpenAIRE |
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