Phase Transitions and Electrochemical Properties of Ionic Liquids and Ionic Liquid-Solvent Mixtures
| Autor: | Alina Ciach, Carolina Cruz |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Phase transition
Materials science Differential capacitance demixing phase transition Pharmaceutical Science Ionic bonding Thermodynamics Review 02 engineering and technology 010402 general chemistry Electrochemistry 01 natural sciences Analytical Chemistry Ion ionic liquids chemistry.chemical_compound QD241-441 Drug Discovery Physical and Theoretical Chemistry supercapacitors Organic Chemistry effects of confinement in ionic systems 021001 nanoscience & nanotechnology 0104 chemical sciences Condensed Matter::Soft Condensed Matter Solvent differential capacitance chemistry ionic liquid-solvent mixtures electrical double layer Chemistry (miscellaneous) Ionic liquid Electrode Molecular Medicine 0210 nano-technology |
| Zdroj: | Molecules Molecules, Vol 26, Iss 3668, p 3668 (2021) |
| ISSN: | 1420-3049 |
| Popis: | Recent advances in studies of ionic liquids (IL) and ionic liquid–solvent mixtures are reviewed. Selected experimental, simulation, and theoretical results for electrochemical, thermodynamical, and structural properties of IL and IL-solvent mixtures are described. Special attention is paid to phenomena that are not predicted by the classical theories of the electrical double layer or disagree strongly with these theories. We focus on structural properties, especially on distribution of ions near electrodes, on electrical double layer capacitance, on effects of confinement, including decay length of a dissjoining pressure between confinig plates, and on demixing phase transition. In particular, effects of the demixing phase transition on electrochemical properties of ionic liquid–solvent mixtures for different degrees of confinement are presented. |
| Databáze: | OpenAIRE |
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