Saddle Shaped Hexaaryl[a,c,fg,j,l,op]tetracenes from 4,5,9,10-Tetrafunctionalized Pyrenes

Autor:	Ralph Rieger, Volker Enkelmann, Klaus Müllen, Lukas Zöphel
Rok vydání:	2011
Předmět:	chemistry.chemical_compound Tetracene Chemistry Stereochemistry Organic Chemistry Pyrene Saddle-shaped Crystal structure Physical and Theoretical Chemistry Biochemistry Saddle Electronic properties Stille reaction
Zdroj:	Organic Letters. 13:4506-4509
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol2016516
Popis:	A new K-region functionalized pyrene is presented which was used as a building block for the straightforward synthesis of hexaaryl[a,c,fg,j,l,op]tetracene via fourfold Stille coupling and subsequent cyclodehydrogenation. Electronic properties and crystal structures are provided and reveal a saddle conformation for the curved hexaarylated tetracenes.(1)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::99be7ee7a98aeea39e3d7ff232dfd12d https://doi.org/10.1021/ol2016516 Zobrazit plný text záznamu