First homoleptic MIC and heteroleptic NHC–MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
| Autor: | Eduardo Peris, Dmitry G. Gusev, Carmen Mejuto, Gregorio Guisado-Barrios |
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| Rok vydání: | 2015 |
| Předmět: |
Tris
Transition-Metals Supramolecular chemistry Salt (chemistry) AU-I Molecular Square Catalytic-Properties Supramolecular Chemistry Catalysis Mesoionic Carbenes chemistry.chemical_compound Transition metal Polymer chemistry Materials Chemistry Organic chemistry Homoleptic Dicarbene Building-Blocks chemistry.chemical_classification Structural Features N-Heterocyclic Carbenes Metals and Alloys General Chemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Ceramics and Composites Polycarbene Ligands |
| Zdroj: | Repositori Universitat Jaume I Universitat Jaume I |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c5cc05114b |
| Popis: | The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag analogue to form the corresponding heteroleptic NHC–MIC silver cage in an unusual reaction involving the simultaneous exchange of the tris-NHC and tris-MIC ligands. MINECO (CTQ2014-51999-P) and UJI (P11B2014-02). Published version |
| Databáze: | OpenAIRE |
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