Total Synthesis of (+)-Cyanthiwigin AC
Autor: | Laird A. Trimble, Reddy Tj, Bordeau G |
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Rok vydání: | 2007 |
Předmět: |
chemistry.chemical_classification
Ketone Alkylation Chemistry Hydrolysis Organic Chemistry Molecular Conformation Total synthesis Stereoisomerism General Medicine Ketones Biochemistry Medicinal chemistry Molecular conformation Porifera chemistry.chemical_compound Cyanthiwigin AC Animals Indicators and Reagents Physical and Theoretical Chemistry Diterpenes Derivative (chemistry) |
Zdroj: | ChemInform. 38 |
ISSN: | 1522-2667 0931-7597 |
DOI: | 10.1002/chin.200714185 |
Popis: | A 13-step synthesis of (+)-cyanthiwigin-AC (2) from (+)-Hajos-Parrish ketone derivative 8b and dimesylate 9c employing deconjugative spiro-bis-alkylation strategy is described. [reaction: see text]. |
Databáze: | OpenAIRE |
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