Eu(III) removal by tetrabutylammonium di-hydrogen phosphate (TBAH2P) functionalized polymers
| Autor: | Narcis Duteanu, Corneliu Mircea Davidescu, Petru Negrea, Mihaela Ciopec, Adina Negrea, Andreea Gabor |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
chemistry.chemical_classification
Chemistry General Chemical Engineering Infrared spectroscopy 02 engineering and technology General Chemistry Amberlite Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences lcsh:Chemistry chemistry.chemical_compound Adsorption lcsh:QD1-999 Surface modification Cellulose Fourier transform infrared spectroscopy 0210 nano-technology Dispersion (chemistry) Nuclear chemistry |
| Zdroj: | Arabian Journal of Chemistry, Vol 13, Iss 1, Pp 3534-3545 (2020) |
| ISSN: | 1878-5352 |
| DOI: | 10.1016/j.arabjc.2018.12.005 |
| Popis: | Polymers involved as adsorbent materials during Eu(III) removal tests were prepared by functionalization of a natural polymer – cellulose, and a commercial one represented by Amberlite XAD7. As extractant, we used tetrabutil ammonium di-hydrogen phosphate (TBAH2P) which is a cheap and environmentally friendly product. Impregnated polymers using a rotavapor system in which the quaternary ammonium salt used as extractant was concentrated on to the used polymer. Later obtained materials were characterized by Fourier Transformed Infrared Spectroscopy (FTIR) and X-Ray electron dispersion (EDX). During experimental test we determine pH, contact time, Eu(III) initial concentration and temperature effect on the functionalized polymers adsorption capacity. Therewith for both functionalized polymers, a comparison was made between the adsorption process characteristics based on kinetics and thermodynamic studies. Keywords: Europium, Cellulose, Amberlite XAD7, Adsorption, Adsorption isotherm |
| Databáze: | OpenAIRE |
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