| Autor: |
Giuseppe Resnati, Arbin Rajbanshi, Melchiorre F. Parisi, Tullio Pilati, Christer B. Aakeröy, Pierangelo Metrangolo, John Desper |
| Rok vydání: |
2012 |
| Předmět: |
|
| Zdroj: |
CrystEngComm. 14:6366 |
| ISSN: |
1466-8033 |
| DOI: |
10.1039/c2ce26173a |
| Popis: |
A halogen-bonded capsule is obtained via directed assembly of a rigid tetra(3-pyridyl) cavitand and a flexible tetra(4-iodotetrafluorophenyl)calix[4]arene. The pyridyl nitrogen atoms from one cavitand molecule interact with the iodine atoms of a single calixarene molecule through short and directional I⋯N halogen bonds. The flexibility of the ethylenedioxy moieties on the calixarene platform results in positional flexibility of the iodotetrafluorobenzene sites which, coupled with a supramolecular chelating effect, allow for an effective partner-induced geometric fitting between four nitrogen atoms on the cavitand and four iodine atoms on the calixarene. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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