Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations

Autor: Ingrid F. Silva, Yves Journaux, Bernd Engels, Willian X. C. Oliveira, Walace D. do Pim, Carlos B. Pinheiro, Emerson F. Pedroso, Humberto O. Stumpf, Miguel Julve, Ivo Krummenacher, Cynthia L. M. Pereira, Felipe Fantuzzi, Holger Braunschweig, Joan Cano, Eufrânio N. da Silva Júnior
Rok vydání: 2021
Předmět:
Zdroj: Dalton transactions (Cambridge, England : 2003). 50(36)
ISSN: 1477-9234
Popis: We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures.
Databáze: OpenAIRE