Molecularly Conductive Behavior of Blended Polymer Electrolyte-based CMC/PVA
| Autor: | Dishen Zhang, Yuki Nagao, Ahmad Salihin Samsudin, Noor Saadiah Mohd Ali |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis Materials science blended polymer electrolytes carboxyl methylcellulose ionic conductivity structural studies Electrolyte Polymer Polyvinyl alcohol Dielectric spectroscopy Carboxymethyl cellulose chemistry.chemical_compound chemistry Chemical engineering lcsh:TA1-2040 medicine Thermal stability Fourier transform infrared spectroscopy lcsh:Engineering (General). Civil engineering (General) medicine.drug |
| Zdroj: | Makara Journal of Technology, Vol 23, Iss 1, Pp 27-31 (2019) |
| ISSN: | 2356-4539 2355-2786 |
| Popis: | This study investigated the electrical conduction and structural behavior of blended polymer electrolyte (BPE)-based carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) in the development of solid-state electrochemical devices. Based on impedance spectroscopy and correlating Fourier transform infrared (FTIR) with thermogravimetric analysis, a framework was proposed to explain the structural enhancement of the BPE system. As revealed by FTIR, the optimum conductivity of CMC/PVA BPEs was 9.21 × 10−6 Scm−1 for 80:20 composition attributed to the intermolecular attraction between the polymers. Thermal stability of the CMC/PVA was influenced by the formation of a hydrogen bond between the hydroxyl (-OH), carboxylate (-COO-), and ether linkage (-COC-) functional groups. The finding provides insights into blended polymer electrolyte-based CMC/PVA, which is beneficial in designing safe, thin, and lightweight energy storage devices. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|