Electron transfer between a lutetium bisphthalocyanine and FeIII/II across liquid|liquid interfaces between water and dichlorohexane or nitrobenzene; influence of coupling with ion transfer
| Autor: | François Quentel, Mickaël Rimboud, Catherine Elleouet, Maurice L’Her |
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| Přispěvatelé: | Chimie, Electrochimie Moléculaires et Chimie Analytique (CEMCA), Institut Brestois Santé Agro Matière (IBSAM), Université de Brest (UBO)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC) |
| Rok vydání: | 2011 |
| Předmět: |
020209 energy
General Chemical Engineering Inorganic chemistry Analytical chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 01 natural sciences Analytical Chemistry Ion Electron transfer Nitrobenzene chemistry.chemical_compound [CHIM.ANAL]Chemical Sciences/Analytical chemistry Spectrophotometry 0202 electrical engineering electronic engineering information engineering Electrochemistry medicine Voltammetry Aqueous solution medicine.diagnostic_test Chemistry uIIIbisphthalocyanine Hexacyanoferrates Lutetium 0104 chemical sciences Coupling (electronics) W|DCH and W|NB microinterfaces |
| Zdroj: | Journal of electroanalytical chemistry and interfacial electrochemistry Journal of electroanalytical chemistry and interfacial electrochemistry, Elsevier, 2011, 660, pp.178-184. ⟨10.1016/j.jelechem.2011.06.028⟩ |
| ISSN: | 1572-6657 0022-0728 |
| DOI: | 10.1016/j.jelechem.2011.06.028 |
| Popis: | International audience; The electron transfer across the liquid|liquid interface between aqueous solutions (W) of FeIII/II compounds (hexacyanoferrates, chlorides) and a (t-butyl) substituted LuIIIbisphthalocyanine in dichlorohexane (DCH) or nitrobenzene (NB), has been studied by voltammetry at a microinterface and by spectrophotometry. The electron transfer wave has been observed only at the W|DCH. Coupling with an ion transfer facilitates this electron transfer: the LuIIIbisphthalocyanine has been oxidized or reduced across the W|NB interface, depending on the ion establishing the interfacial potential. |
| Databáze: | OpenAIRE |
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