Hydrocarbon Diffusion in Mesoporous Carbon Materials: Implications for Unconventional Gas Recovery
Autor: | Daniel Ferry, Eric Chaput, Yann Magnin, Rachel Jorand, Jérémie Berthonneau, Olivier Grauby, Nicolas Chanut, Roland J.-M. Pellenq, Franz J. Ulm |
---|---|
Přispěvatelé: | Laboratoire de Physique Théorique et Modélisation (LPTM - UMR 8089), Centre National de la Recherche Scientifique (CNRS)-CY Cergy Paris Université (CY), Department of Civil and Environmental Engineering [Cambridge] (CEE), Massachusetts Institute of Technology (MIT), Matériaux divisés, interfaces, réactivité, électrochimie (MADIREL), Aix Marseille Université (AMU)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre Interdisciplinaire de Nanoscience de Marseille (CINaM), Centre National de la Recherche Scientifique (CNRS)-Aix Marseille Université (AMU), Institute for Applied Geophysics and Geothermal Energy, Rheinisch-Westfälische Technische Hochschule Aachen (RWTH), Aix Marseille Université (AMU)-Centre National de la Recherche Scientifique (CNRS), Rheinisch-Westfälische Technische Hochschule Aachen University (RWTH) |
Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: |
Molecular diffusion
Materials science Fluid mechanics Kerogen 02 engineering and technology Microporous material Neutron scattering Molecular dynamics 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences molecular diffusion Chemical physics Volume fraction [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] General Materials Science Diffusion (business) 0210 nano-technology Mesoporous material Porosity Tomography Methane Green-Kubo equation |
Zdroj: | ACS Applied Nano Materials ACS Applied Nano Materials, American Chemical Society, 2020, 3 (8), pp.7604-7610. ⟨10.1021/acsanm.0c01191⟩ ACS Applied Nano Materials, 2020, 3 (8), pp.7604-7610. ⟨10.1021/acsanm.0c01191⟩ |
ISSN: | 2574-0970 |
Popis: | International audience; Methane diffusion in micro- and mesopores of carbonaceous materials is dominated by molecular interactions with the pore walls. As a consequence, the fluid molecules are mainly in a diffusive regime and the laws of fluid mechanics are not directly applicable. A method called the “free volume theory” has been successfully used by different authors to study the diffusion of n-alkanes into microporous carbons. However, we show in this paper that such a method fails to describe the dynamical properties of methane in porous hosts presenting both micro- and mesopores. We further evidence that this theory is limited to structures whose pore diameters are lower than ∼3 nm. We then propose a simple scaling method based on the micro- and mesoporous volume fraction in order to predict diffusion coefficients. This method only requires the knowledge of (i) the host microporous volume fraction and (ii) the self-diffusion coefficient in micropores smaller than 3 nm, which can be obtained using the “free volume theory”, quasi-elastic neutron scattering experiments, or atomistic simulations. |
Databáze: | OpenAIRE |
Externí odkaz: |