Molecular structure of novel heterobimetallic thiolate [Cu(PPh3)]4(ZnCl)2(SEt)6.6THF

Autor: Anna L. Sudlow, Kieran C. Molloy, Gabriele Kociok-Köhn
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: Main Group Metal Chemistry, Vol 38, Iss 3-4, Pp 117-119 (2015)
ISSN: 2191-0219
0792-1241
Popis: Heterobimetallic thiolate [Cu(PPh3)]4(ZnCl)2 (SEt)6 has been synthesised and characterised by X-ray crystallography as a THF solvate. It contains the first structurally characterised example of a CuI-S(R)-ZnII linkage and only the second species type to embody the CuI-S-ZnII triad.
Databáze: OpenAIRE