Interaction of cobalt(II) and nickel(II) with a gamma-linked, bis-beta-diketone ligand to yield an unusual coordination motif

Autor:	John C. McMurtrie, Peter Turner, Gang Wei, Shi-Xia Luo, Xiao-Yi Zhang, Huai-wu Zhu, Leonard F. Lindoy, Bai-Shu Zheng
Rok vydání:	2005
Předmět:	Ligand Stereochemistry Oxygen donor chemistry.chemical_element Sulfur Inorganic Chemistry Nickel Crystallography β diketone chemistry.chemical_compound chemistry Yield (chemistry) Cobalt Derivative (chemistry)
Zdroj:	Dalton transactions (Cambridge, England : 2003). (8)
ISSN:	1477-9226
Popis:	Discrete cobalt(II) and nickel(II) complexes of type ML (where L is a bis(2,4-pentanedionate) derivative incorporating a -SCH2CH2S- bridge between the gamma-carbons of respective beta-diketone units) have been synthesised and represent the first examples in which a gamma-substituted, thioether-containing beta-diketone ligand coordinates via a sulfur and oxygen donor in preference to the classical coordination mode involving both beta-diketonate oxygens.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9866db67b3ab55616af7f8c7b1a7d0b7 https://pubmed.ncbi.nlm.nih.gov/15824769 Zobrazit plný text záznamu