Base-promoted tautomerization of imidazole ligands to N-heterocyclic carbenes and subsequent transmetalation reaction
| Autor: | Bernabé F. Perandones, Javier Ruiz |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) Transition metal carbene complex Imidazole ligand chemistry.chemical_element General Chemistry Manganese Biochemistry Medicinal chemistry Tautomer Catalysis chemistry.chemical_compound Transmetalation Colloid and Surface Chemistry chemistry Imidazole Organic chemistry Carbene |
| Zdroj: | Journal of the American Chemical Society. 129(30) |
| ISSN: | 0002-7863 |
| Popis: | Imidazole complexes of manganese(I) are transformed into their corresponding N-heterocyclic carbene derivatives by means of acid−base treatments; the subsequent sequential transmetalation reaction of the carbene to gold(I) proceeds through isolable heterometallic intermediate species. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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