C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation
| Autor: | Kwok-Kong Tony Mong, Patteti Venukumar, Arun B. Ingle, Jyh-Herng Ruei |
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| Rok vydání: | 2015 |
| Předmět: |
Glycosylation
Metals and Alloys Stereoisomerism General Chemistry Bond formation Catalysis Glycoside formation Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Group (periodic table) Carbohydrate Conformation Materials Chemistry Ceramics and Composites Organic chemistry Component (group theory) Glycosides Protecting group |
| Zdroj: | Chemical Communications. 51:5394-5397 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | We reported a remote control glycosylation method using the picoloyl protecting group for 2-deoxy-β-glycosidic bond formation. The method is applicable to various 2-deoxythioglycosyl donors and the utility is illustrated by the synthesis of a deoxytrisaccharide component of landomycins. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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