Self-threading of a poly(ethylene glycol) chain in a cyclodextrin-ring: control of the exchange dynamics by chain length
| Autor: | Yoshinori Takashima, Akira Harada, Hiroki Nakajima, Masahiko Miyauchi, Youhei Inoue, Hiroyasu Yamaguchi |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Cyclodextrin Chemistry technology industry and agriculture General Chemistry Ring (chemistry) Biochemistry Catalysis Inclusion compound chemistry.chemical_compound Colloid and Surface Chemistry Chain (algebraic topology) Polymer chemistry PEG ratio Threading (protein sequence) Ethylene glycol |
| Zdroj: | Journal of the American Chemical Society. 128(28) |
| ISSN: | 0002-7863 |
| Popis: | Poly(ethylene glycol) (PEG)-substituted cyclodextrins (CDs) with different chain lengths have been synthesized. PEG-substituted CDs formed self-threading complexes in aqueous solutions, and the conformational exchange dynamics between self-threading and dethreading could be regulated by its chain length. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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