Oxidative Coupling of Terminal Rhenium Pnictide Complexes

Autor:	Max C. Holthausen, Josh Abbenseth, Martin Diefenbach, Lukas Alig, Alexander Hinz, Christian Würtele, Jose M. Goicoechea, Sven Schneider
Rok vydání:	2019
Předmět:	Phosphide 010405 organic chemistry Decarbonylation chemistry.chemical_element General Chemistry General Medicine Rhenium Pyrazole ligands 010402 general chemistry 01 natural sciences Catalysis Arsenide 0104 chemical sciences 3. Good health Metal Crystallography chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Oxidative coupling of methane Pnictogen
Zdroj:	Angewandte Chemie International Edition
ISSN:	1521-3757 0044-8249
DOI:	10.1002/ange.201905130
Popis:	The isolation of rhenium(V) complexes with terminal phosphide and arsenide ligands was achieved upon decarbonylation of rhenium(III) pnictaethynolates. One-electron oxidation of the pnictide complexes yielded Pn-Pn (Pn=P, As) coupling products, which were spectroscopically and crystallographically characterized. Computational bond analysis suggests that these complexes are best described as {Pn2 }0 complexes that are stabilized by donor-acceptor interactions with the metal and a pyrazole ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::976f0466278b09becb3a91eda2ab0432 https://doi.org/10.1002/ange.201905130 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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