Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage
| Autor: | Satoshi Suzuki, Tatsuro Toda, Shigeki Kuwata |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Carbon disulfide
010405 organic chemistry Chemistry Hydrogen bond Metals and Alloys chemistry.chemical_element General Chemistry Pyrazole 010402 general chemistry Diprotic acid 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ruthenium Supramolecular assembly Pincer movement chemistry.chemical_compound Polymer chemistry Materials Chemistry Ceramics and Composites Linker |
| Zdroj: | Chemical Communications. 55:1028-1031 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c8cc08384c |
| Popis: | Partial dehydrobromination of a diprotic pincer-type ruthenium complex in the presence of a rigid 1,3-bis(diphenylphosphino)benzene linker provided a dinuclear cage containing a guest template KBr surrounded by hydrogen bonds and electrostatic interactions. Dinitrogen and carbon disulfide were encapsulated into the cage with proton channels formed by the pyrazole arms in the pincer ligands. |
| Databáze: | OpenAIRE |
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