Bis-exo-2-norbornylboron triflate for stereospecific enolization of 3,3,3-trifluoropropionates

Autor:	P. Veeraraghavan Ramachandran, Pravin D. Gagare, Gowrisankar Parthasarathy
Rok vydání:	2010
Předmět:	Molecular Structure Chemistry Organic Chemistry Fluorine Compounds Stereoisomerism Keto–enol tautomerism Biochemistry Norbornanes Stereospecificity Reagent Organic chemistry Methyldopa Physical and Theoretical Chemistry Propionates Trifluoromethanesulfonate
Zdroj:	Organic letters. 12(20)
ISSN:	1523-7052
Popis:	The first boron-mediated enolization−aldolization of 3,3,3-trifluoropropionates has been reported. The preparation and application of bis-exo-bicyclo[2.2.1]heptan-2-ylboron triflate as a superior reagent for diastereospecific enolization has also been described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::97441f1781b5da4f35fdae37f7b3609a https://pubmed.ncbi.nlm.nih.gov/20849128 Zobrazit plný text záznamu