Flexible, Large-Area Organic Solar Cells With Improved Performance Through Incorporation of CoFe2O4 Nanoparticles in the Active Layer
| Autor: | Juliana Luiza da Silva Martins, Igor F. Vasconcelos, Diego Bagnis, Francisco Anderson de Sousa Lima, Rodrigo Queiros de Almeida, M. S. Pereira, Eduardo B. Barros, Antonio Sergio Bezerra Sombra |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Organic solar cell Organic solar cells Mechanical Engineering Photovoltaic system Doping Energy conversion efficiency Nanoparticle engineering.material Condensed Matter Physics Active layer power conversion efficiency Coating Chemical engineering Mechanics of Materials P3HT:PCBM films TA401-492 engineering General Materials Science PCBM films [P3HT] CoFe2O4 nanoparticles stability and lifetime Materials of engineering and construction. Mechanics of materials Current density |
| Zdroj: | Materials Research, Volume: 22, Issue: 6, Article number: e20190417, Published: 13 JAN 2020 CIÊNCIAVITAE Materials Research, Vol 22, Iss 6 (2020) Materials Research v.22 n.6 2019 Materials research (São Carlos. Online) Universidade Federal de São Carlos (UFSCAR) instacron:ABM ABC ABPOL |
| Popis: | Cobalt ferrite (CoFe2O4) nanoparticles (NPs), with an average diameter of about 4-10 nm, were produced by the proteic sol-gel method and successfully doped into the active layer of poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) organic solar cells. Pristine and CoFe2O4 NPs-doped blends of P3HT:PCBM were dispersed in a mixture of o-xylene:tetralin (1 mg/mL) based non-halogenated solvents and deposited via a semi-industrial blade coating process on flexible substrates to fabricate large area (0.55 cm2), flexible organic solar cells with inverted configuration. The main focus of this study aims to assess the influence of NPs on the efficiency, stability and lifetime of the produced devices. From the photovoltaic parameters it was observed that the optimization of the bulk-heterojunction through the incorporation of CoFe2O4 NPs resulted in increased short-circuit current density. As a result, the power conversion efficiency of doped devices increased by 10 % when compared with the undoped reference devices. Tests of lifetime and stability were performed using International Summit on OPV Stability (ISOS) protocols ISOS-D-3, ISOS-O-1 and ISOS-L-1. For the duration of the tests (1200 h), the results showed that doped cells presented performances at least comparable with those of reference cells. |
| Databáze: | OpenAIRE |
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