Crystalline Molecular Machines: A Quest Toward Solid-State Dynamics and Function

Autor: Jose E. Nunez, Tinh Alfredo V Khuong, Carlos E. Godinez, Miguel A. Garcia-Garibay
Rok vydání: 2006
Předmět:
Zdroj: Accounts of Chemical Research. 39:413-422
ISSN: 1520-4898
0001-4842
Popis: Complex molecular machinery may be envisioned as densely packed, multicomponent, self-assemblying systems built with high structural precision to control the dynamics of one or more internal degrees of freedom. With molecular gyroscopes as a test, we describe a general strategy to design crystals capable of supporting structurally programmed molecular motions, a practical approach to their synthesis, convenient strategies to characterize their solid-state dynamics, and potential applications based on polar structures responding collectively to external fields.
Databáze: OpenAIRE