Membraneless flow battery leveraging flow-through heterogeneous porous media for improved power density and reduced crossover
Autor: | Cullen R. Buie, Martin Z. Bazant, Matthew E. Suss, Kameron M. Conforti, Laura M. Gilson |
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Přispěvatelé: | Massachusetts Institute of Technology. Department of Chemical Engineering, Massachusetts Institute of Technology. Department of Mathematics, Massachusetts Institute of Technology. Department of Mechanical Engineering, Suss, Matthew, Conforti, Kameron Michael, Gilson, Laura M., Buie, Cullen, Bazant, Martin Z |
Rok vydání: | 2016 |
Předmět: |
Chemical Physics (physics.chem-ph)
Materials science General Chemical Engineering Crossover FOS: Physical sciences 02 engineering and technology General Chemistry Mechanics 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Flow battery 0104 chemical sciences Membrane Flow (mathematics) Physics - Chemical Physics 0210 nano-technology Porous medium Current density Power density |
Zdroj: | arXiv |
ISSN: | 2046-2069 |
DOI: | 10.1039/c6ra22608f |
Popis: | A key factor preventing the market penetration of renewable, intermittent energy sources, such as solar, wind and wave, is the lack of cost-effective energy storage options to counteract intermittency. Here, we propose and demonstrate a novel flow battery architecture that replaces traditional ion-exchange membranes with less expensive heterogeneous flow-through porous media. We present an experimentally-validated model which demonstrates that our architecture promises reduced crossover of reactive species compared to typical membraneless systems employing co-laminar flows in open channels. In addition, our prototype battery exhibits significantly improved power density (0.925 W/cm2) and maximum current density (3 A/cm2) compared to previous membraneless systems. |
Databáze: | OpenAIRE |
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