Highly Emissive Multipurpose Organoplatinum(II) Metallacycles with Contrasting Mechanoresponsive Features

Autor:	Ya Yin, Zhao Chen, Run-Hao Li, Fan Yi, Xiao-Cui Liang, Shi-Qi Cheng, Kai Wang, Yue Sun, Yi Liu
Rok vydání:	2022
Předmět:	Inorganic Chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 61:2883-2891
ISSN:	1520-510X 0020-1669
DOI:	10.1021/acs.inorgchem.1c03563
Popis:	The development of supramolecular coordination complexes (SCCs) with a bright aggregate state or mechanical-stimuli-responsive luminescence is very significant and challenging. Herein, we report the synthesis of three different supramolecular platinum(II) metallacycles via coordination-driven self-assembly of a diplatinum(II) acceptor and organic donors with a triphenylamine, carbazole, or tetraphenylethylene moiety. The triphenylamine-modified SCC exhibits aggregation-induced emission enhancement (AIEE) but no mechanofluorochromism. The carbazole and tetraphenylethylene-based SCCs exhibit changes in aggregate fluorescence and also exhibit reversible mechanofluorochromism. This work not only reports three rare metallacycles with AIEE, aggregate fluorescence change, or mechanofluorochromic nature but also explores their potential applications in cell imaging and solid-state lighting.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9652b2a0c3449984a4a78c67f4da66d1 https://doi.org/10.1021/acs.inorgchem.1c03563 Zobrazit plný text záznamu