Esterification by Redox Dehydration Using Diselenides as Catalytic Organooxidants

Autor:	Thomas C. Pickel, Lanny S. Liebeskind, Srirama Murthy Akondi
Rok vydání:	2019
Předmět:	inorganic chemicals 010405 organic chemistry Chemistry Aryl Organic Chemistry 010402 general chemistry medicine.disease 01 natural sciences Redox 0104 chemical sciences Catalysis chemistry.chemical_compound Reagent Polymer chemistry medicine Dehydration Stoichiometry
Zdroj:	The Journal of Organic Chemistry. 84:4954-4960
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.8b02765
Popis:	Ortho-functionalized aryl diselenides are catalytic (5.0 mol %) oxidants for the construction of esters from carboxylic acids and alcohols in the presence of stoichiometric triethyl phosphite and dioxygen in air as the terminal redox reagents (redox dehydration conditions). The reaction proceeds through the intermediacy of the anhydride and requires the presence of 10% DMAP to drive the esterification.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9641bc97e50defc7e84890c4e2a4ec42 https://doi.org/10.1021/acs.joc.8b02765 Zobrazit plný text záznamu