The Driving Mechanism Behind Attrition-Enhanced Deracemization

Autor:	J. Michael McBride, Bernard Kaptein, Hugo Meekes, John C. Tully, Wim L. Noorduin, Richard M. Kellogg, Willem J. P. van Enckevort, Elias Vlieg
Přispěvatelé:	Stratingh Institute of Chemistry
Jazyk:	angličtina
Rok vydání:	2010
Předmět:	education.field_of_study crystallization Chemistry Population chiral symmetry breaking deracemization General Chemistry General Medicine Solid State Chemistry ablation Catalysis law.invention Crystallography law Phase (matter) clusters Crystallization education Enantiomeric excess Net flux
Zdroj:	Angewandte Chemie International Edition, 49(45), 8435-8438. WILEY-V C H VERLAG GMBH Angewandte Chemie. International Edition, 49, 8435-8438 Angewandte Chemie. International Edition, 49, 45, pp. 8435-8438
ISSN:	1521-3773 1433-7851
DOI:	10.1002/ange.201002036
Popis:	Change of heart: A solution-phase enantiomeric excess that has the handedness of the minor population of the solid phase is observed during grinding of a slurry of racemic conglomerate crystals. This excess is the driving force for a net flux of molecules from crystals of the minor handedness to crystals of the major handedness, thus explaining the complete deracemization of the solid phase.
Databáze:	OpenAIRE
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