Ullmann Reaction of Aryl Chlorides on Various Surfaces and the Application in Stepwise Growth of 2D Covalent Organic Frameworks
| Autor: | Xin-Yan Wu, Deng Yuan Li, Dingwang Yuan, Chen Hui Shu, Cheng Xin Wang, Ziliang Shi, Pei Nian Liu, Ke Ji Shi |
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| Rok vydání: | 2016 |
| Předmět: |
Aryl
Organic Chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry Coupling reaction 0104 chemical sciences law.invention Ullmann reaction chemistry.chemical_compound chemistry Covalent bond law Polymer chemistry Organic chemistry Molecule Reactivity (chemistry) Density functional theory Physical and Theoretical Chemistry Scanning tunneling microscope 0210 nano-technology |
| Zdroj: | Organic Letters. 18:1282-1285 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.6b00172 |
| Popis: | On-surface Ullmann coupling reaction of aryl chlorides has been achieved on Cu(111), Ag(111), and Au(111), and the mechanism has been investigated on the single molecule level using scanning tunneling microscopy and density functional theory. The different reactivity of the aryl halides was utilized to design a stepwise on-surface synthesis, which affords a zigzag template and then converts to 2D porous networks. |
| Databáze: | OpenAIRE |
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