Dendrimers Containing Ferrocene and Porphyrin Moieties: Synthesis and Cubic Non-Linear Optical Behavior
| Autor: | Karla E. Sanchez-Montes, Irina Victorovna Lijanova, Elena I. Klimova, Simón Hernández-Ortega, Eric G. Morales-Espinoza, José L. Maldonado, Marcos Martínez-García, Gabriel Ramos-Ortiz, Tatiana Klimova |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: |
Spectrometry
Mass Electrospray Ionization Magnetic Resonance Spectroscopy Porphyrins Materials science Optical Phenomena Metallocenes Chemical structure Electrospray ionization Pharmaceutical Science Crystallography X-Ray Photochemistry Mass spectrometry Article Analytical Chemistry dendrimers lcsh:QD241-441 chemistry.chemical_compound lcsh:Organic chemistry Dendrimer Drug Discovery Molecule Ferrous Compounds Physical and Theoretical Chemistry Molecular Structure Organic Chemistry ferrocene Nuclear magnetic resonance spectroscopy Porphyrin non-linear optics Crystallography Ferrocene chemistry Chemistry (miscellaneous) Molecular Medicine porphyrin |
| Zdroj: | Molecules, Vol 15, Iss 4, Pp 2564-2575 (2010) Molecules Volume 15 Issue 4 Pages 2564-2575 |
| ISSN: | 1420-3049 |
| Popis: | Dendrons with ferrocenyl ended groups joined by styryl moieties were attached to a porphyrin core. All the dendrons used for dendrimer synthesis showed trans configuration. The chemical structure of the first generation dendron was confirmed by X-ray crystallographic studies. The structure of the synthesized dendrimers was confirmed by 1H- and 13C-NMR, electrospray mass spectrometry and elemental analysis. Cubic non-linear optical behavior of the ferrocene and porphyrin-containing dendrimers was studied in solid thin films by THG Maker-Fringe technique at 1,260 nm. |
| Databáze: | OpenAIRE |
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