Synthesis and complexes of a constrained-cavity Schiff-base dipyrrin macrocycle

Autor:	Jason B. Love, Karlotta van Rees
Rok vydání:	2021
Předmět:	chemistry.chemical_classification Schiff base chemistry.chemical_element Salt (chemistry) law.invention Inorganic Chemistry chemistry.chemical_compound Elimination reaction chemistry law Polymer chemistry Lithium Crystallization Spectroscopy
Zdroj:	van Rees, K & Love, J B 2021, ' Synthesis and complexes of a constrained-cavity Schiff-base dipyrrin macrocycle ', Dalton Transactions, vol. 50, no. 5, pp. 1610-1613 . https://doi.org/10.1039/d1dt00175b
ISSN:	1477-9234
DOI:	10.1039/d1dt00175b
Popis:	A new constrained-cavity [1 + 1] Schiff-base dipyrrin macrocycle comprising an N4donor-pocket has been synthesised by spontaneous oxidation andin situcrystallisation. Access to Fe(ii) and Zn(ii) complexes is achieved by salt elimination reactions of the lithium salt. All compounds have been characterised by NMR and UV-vis spectroscopy, X-ray crystallography, and DFT analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::95b875792ea4009cac6cb0af1d12e6bb https://pubmed.ncbi.nlm.nih.gov/33508062 Zobrazit plný text záznamu