Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts
| Autor: | Megumi Kayanuma, Thibaut Stoll, Martina Sandroni, Fabrice Odobel, Carmen E. Castillo, Jérôme Fortage, Chantal Daniel, Marie-Noëlle Collomb |
|---|---|
| Přispěvatelé: | Département de Chimie Moléculaire (DCM), Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (DCM - CIRE), Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Chimie de Strasbourg, Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Chimie Et Interdisciplinarité : Synthèse, Analyse, Modélisation (CEISAM), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Hydrogen
chemistry.chemical_element Electron donor Photochemistry 7. Clean energy Redox Catalysis Rhodium Inorganic Chemistry Bipyridine chemistry.chemical_compound chemistry Materials Chemistry [CHIM]Chemical Sciences Photosensitizer Physical and Theoretical Chemistry ComputingMilieux_MISCELLANEOUS Hydrogen production |
| Zdroj: | Coordination Chemistry Reviews Coordination Chemistry Reviews, Elsevier, 2015, 304-305, pp.20-37. ⟨10.1016/j.ccr.2015.02.002⟩ |
| ISSN: | 0010-8545 |
| DOI: | 10.1016/j.ccr.2015.02.002⟩ |
| Popis: | Solar driven water-splitting into hydrogen (H 2 ) and oxygen (O 2 ) has emerged as a very attractive sustainable approach to produce the fuel H 2 , which can be considered as promising clean and renewable energy carrier for the future. The development of homogeneous multi-component photocatalytic systems for the reduction of protons to H 2 based on molecular compounds has experienced considerable growth since the end of the seventies. Such systems are generally composed of a light-harvesting antenna (photosensitizer), a hydrogen-evolving catalyst and a sacrificial electron donor coupled in some cases with an electron mediator. This review will survey the literature on homogeneous molecular multi-component photocatalytic systems for hydrogen production using rhodium complexes as catalysts with a special highlight on those operating in fully aqueous solution. In all of these studies, ruthenium-tris(bipyridine) or heteroleptic cyclometalated iridium complexes have been used as photosensitizers. Rhodium(III) complexes with poly(bipyridyl) ligands have been employed as catalysts in most of the studies. These multi-components photocatalytic systems are based on two different approaches: (i) multi-molecular systems, and (ii) systems involving an assembled structure (photocatalyst) that chemically couples in the same molecule the photosensitizer and the catalyst. |
| Databáze: | OpenAIRE |
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