Light-Activated CO Donor as a Universal CO Surrogate for Pd-Catalyzed and Light-Mediated Carbonylation

Autor:	Ladie Kimberly De La Cruz, Nicola Bauer, Alyssa Cachuela, Wing Sze Tam, Ravi Tripathi, Xiaoxiao Yang, Binghe Wang
Rok vydání:	2022
Předmět:	Carbon Monoxide Molecular Structure Organic Chemistry Physical and Theoretical Chemistry Biochemistry Catalysis Palladium
Zdroj:	Organic Letters. 24:4902-4907
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.2c01726
Popis:	A low-molecular-weight, solid CO surrogate that only requires a low-power LED for activation to release 2 equiv of CO is reported. The surrogate can be universally implemented in various palladium-catalyzed carbonylative transformations. It is also compatible with protocols that employ blue-light to activate conventionally inaccessible substrates such as nonactivated alkyl halides. Furthermore, we demonstrate that the photolabile CO-releasing scaffold can be installed into polymeric materials, thereby creating new materials with CO-releasing capabilities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::94f819497645b99ccb708311d73ee31e https://doi.org/10.1021/acs.orglett.2c01726 Zobrazit plný text záznamu