Enamine-based hole transporting materials for vacuum-deposited perovskite solar cells
| Autor: | Giedre Bubniene, Maria-Grazia La-Placa, Ismail Cihan Kaya, Matas Steponaitis, Maryte Daskeviciene, Michele Sessolo, Vygintas Jankauskas, Henk J. Bolink, Vytautas Getautis, Tadas Malinauskas |
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| Přispěvatelé: | Royal Society of Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Materials science
enamine-based hole transporting materials Energy Engineering and Power Technology 02 engineering and technology 010402 general chemistry 01 natural sciences 7. Clean energy perovskite solar cells Catalysis Enamine chemistry.chemical_compound Vacuum deposition Electric field Deposition (phase transition) Materials vacuum-deposited Cèl·lules fotoelèctriques Perovskite (structure) Renewable Energy Sustainability and the Environment business.industry Energy conversion efficiency 021001 nanoscience & nanotechnology 0104 chemical sciences Thermogravimetry Fuel Technology chemistry Optoelectronics 0210 nano-technology business |
| Zdroj: | Sustainable energy & fuels, Cambridge : Royal Society of Chemistry, 2020, vol. 4, iss. 10, p. 5017-5023 Sustainable Energy & Fuels Steponaitis, Matas La Placa, Maria-Grazia Kaya, Ismail Cihan Bubniene, Giedre Jankauskas, Vygintas Daskeviciene, Maryte Sessolo, Michele Malinauskas, Tadas Bolink, Henk Getautis, Vytautas 2020 Enamine-based hole transporting materials for vacuum-deposited perovskite solar cells Sustainable Energy & Fuels 4 5017 5023 RODERIC. Repositorio Institucional de la Universitat de Valéncia instname RODERIC: Repositorio Institucional de la Universitat de Valéncia Universitat de València |
| ISSN: | 2398-4902 |
| Popis: | In a short period of time, the rapid development of perovskite solar cells attracted a lot of attention in the science community with the record for power conversion efficiency being broken every year. Despite the fast progress in power conversion efficiency there are still many issues that need to be solved before starting large scale commercial applications, such as, among others, the difficult and costly synthesis and usage of toxic solvents for the deposition of hole transport materials (HTMs). We herein report new enamine-based charge transport materials obtained via a simple one step synthesis procedure, from commercially available precursors and without the use of expensive organometallic catalysts. The developed materials demonstrated rapid loss of mass during thermogravimetry analysis suggesting that they could be processed not only using solution processing but also via vacuum deposition. Furthermore, all HTMs demonstrated high charge carrier mobility with H2 possessing the highest mobility of 2.5 × 10−2 cm2 V−1 s−1 under strong electric fields. The investigated materials were employed in vacuum-deposited p–i–n perovskite solar cells and champion devices with enamine H2 demonstrate a PCE of 18.4%. |
| Databáze: | OpenAIRE |
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