Calculation of the CP-CV as a function of temperature close to the melting point in benzene
| Autor: | H. Yurtseven, Ozlem Tari |
|---|---|
| Přispěvatelé: | İstanbul Arel Üniversitesi, Tari, O., Department of Mathematics and Computer Science, Istanbul Arel University, Istanbul, Turkey, Yurtseven, H., Department of Physics, Middle East Technical University, Ankara, Turkey |
| Rok vydání: | 2017 |
| Předmět: |
Heat capacity
Equation of state solid and liquid benzene Fundamental thermodynamic relation Chemistry melting point Thermodynamics molar volume 02 engineering and technology 021001 nanoscience & nanotechnology Condensed Matter Physics Electronic Optical and Magnetic Materials chemistry.chemical_compound Molar volume 020401 chemical engineering Volume (thermodynamics) Materials Chemistry Melting point Physics::Chemical Physics 0204 chemical engineering Physical and Theoretical Chemistry 0210 nano-technology Constant (mathematics) Benzene |
| Zdroj: | Physics and Chemistry of Liquids. 56:660-673 |
| ISSN: | 1029-0451 0031-9104 |
| DOI: | 10.1080/00319104.2017.1376059 |
| Popis: | Tarı İlgin, Özlem (Arel Author) The temperature dependence of the C-P - C-V is calculated at constant pressures using the observed volume data from the literature for solid and liquid benzene near the melting point. Our calculated values are compared with some earlier treatments and we find that they disagree at constant pressures for the solid benzene, whereas for the liquid benzene agreement is reasonable in terms of the order of magnitude between our calculated C-P - C-V and those predicted from the Peng-Robinson equation of state. Our calculated C-P also agrees with the experimental data at normal pressure and has lower values at higher pressures in liquid benzene. Our treatment given here indicates that the C-P - C-V and the heat capacity C-P can be calculated from the molar volume as a function of temperature at constant pressures using the thermodynamic relations for the solid and liquid benzene near the melting point. |
| Databáze: | OpenAIRE |
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