Tandem catalysis: a new approach to polypeptides and cyclic carbonates

Autor:	Emilie Brulé, Sumesh K. Raman, Mathieu J.-L. Tschan, Christophe M. Thomas
Rok vydání:	2014
Předmět:	Tandem Chemistry Metals and Alloys Carbonates General Chemistry Carbon Dioxide Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Anhydrides Materials Chemistry Ceramics and Composites Organic chemistry Peptides Aluminum
Zdroj:	Chemical communications (Cambridge, England). 50(89)
ISSN:	1364-548X
Popis:	A new tandem catalytic system mediates very efficiently and selectively at room temperature two sequential reactions to produce relevant derivatives in one pot. Remarkably, this new concept of catalysis allows the facile synthesis of polypeptides and provides direct access to cyclic carbonates in high yields, through the incorporation of the carbon dioxide released from the initial step, thus achieving full-atom economy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::93d2aaffb46261ba8cd6a2e70ae91a10 https://pubmed.ncbi.nlm.nih.gov/25251079 Zobrazit plný text záznamu