Fluorescent Groups at the Core of Phosphorus Dendrons and Their Properties

Autor: Anne-Marie Caminade, Aurélien Hameau, Kathleen Moineau-Chane Ching, Cédric-Olivier Turrin
Přispěvatelé: Laboratoire de chimie de coordination (LCC), Institut de Chimie de Toulouse (ICT), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS), CNRS
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Helvetica Chimica Acta
Helvetica Chimica Acta, 2023, 106, pp.e202300048. ⟨10.1002/hlca.202300048⟩
ISSN: 0018-019X
1522-2675
DOI: 10.1002/hlca.202300048⟩
Popis: International audience; This review presents the synthesis of dendrons (dendritic wedges) based on cyclotriphosphazene cores, in which one function is a fluorescent group, and the five remaining functions are used for growing the dendritic branches. The growing of the branches is carried out by a divergent method, using a two-step process which implies hydroxybenzaldehyde and the phosphorhydrazide H2NNMeP(S)Cl2. Four different fluorophores have been used, derived from maleimide, julolidine, pyrene, or from a near-infra-red fluorophore. Depending on the type of fluorophore and on the type of terminal functions of the dendrons, different applications have been targeted. One can cite experiments in catalysis or for the elaboration of materials, transfection experiments, the study of anti-cancer properties, and imaging in relation with the human immune system.
Databáze: OpenAIRE
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