High‐ T c 1D Phase‐Transition Semiconductor Photoluminescent Material with Broadband Emission

Autor: Ting‐Ting Ying, Ming‐Yang Wan, Fang‐Xin Wang, Yu Zhang, Yun‐Zhi Tang, Yu‐Hui Tan, Juan Liao, Li‐Juan Wang
Rok vydání: 2023
Předmět:
Zdroj: Chemistry – A European Journal. 29
ISSN: 1521-3765
0947-6539
Popis: One dimensional (1D) organic-inorganic halide hybrid perovskite has the advantages of excellent organic cation modifiability and diversity of inorganic framework structures, which cannot be ignored in the development of multi-functional phase transition materials in photoelectric and photovoltaic devices. Here, we have successfully modified and synthesized an organic-inorganic hybrid perovskite photoelectric multifunctional phase transition material: [C7H13ONCH2F] PbBr3 (1). The synergistic effect of the order double disorder transition of organic cations and the change of the degree of distortion of the inorganic framework leads to its high temperature reversible phase transition point of Tc=374 K/346 K and its ultra-low loss high-quality dielectric switch response. Through in-depth research and calculation, compound 1 also has excellent semiconductor characteristics with a band gap of 3.06 eV and the photoluminescence characteristics of STE broadband emission. Undoubtedly, this modification strategy provides a new choice for the research field of organic-inorganic hybrid perovskite reversible phase transition photoelectric multifunctional materials with rich coupling properties.
Databáze: OpenAIRE
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