Insights into the formation of chiral second sphere coordination complexes with aromatic tris amines: combined single crystal X-ray crystallography and molecular modeling analyses
| Autor: | Lei Li, Antonino Famulari, Javier Martí-Rujas, Stefano Valdo Meille, Ji Gao, Fang Guo, Wenxu Zheng, Massimo Cametti, Jian Tong, Hong-cui Yu |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Popis: | A family of isostructural, chiral supramolecular networks have been obtained in the solid state by exploiting second sphere coordination interactions in the self-assembly of achiral tris amines and with tetrahalometallate and halide ions. Quantum-Mechanical (QM) calculations specific for solid phases provided additional insights into the intramolecular and packing interactions which determine chirality, pointing to a direct effect of the methyl groups of the central benzene ring. |
| Databáze: | OpenAIRE |
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