The full catalytic processing of biomass components
Autor: | Filatova, A., Shimanskaya, E., Sulman, M., Gakipova, D. |
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Jazyk: | ruština |
Rok vydání: | 2017 |
Předmět: | |
ISSN: | 2092-2116 |
DOI: | 10.5281/zenodo.1101147 |
Popis: | In this work, experimental studies aimed at the study of the hydrogenolysis of components of plant biomass with the production of valuable chemical substances have been conducted. Research aimed at the finding of the effective catalytic system allows obtaining a high degree of conversion of the substrate with high selectivity in the processing of all components of the biomass. On the basis of experimental data, it can be concluded that 3% Ru/MN270 catalyst is active in the hydrogenolysis of lignin, cellulose and hemicellulose, and it can be used in a complex processing of biomass. The catalytic system is also stable — the five-time use in the reaction of hydrogenolysis did not lead to the change of activity. {"references":["Ma, J., Yu, W., Wang, M., Jia, X., Lu, F., & Xu, J. (2013). Advances in selective catalytic transformation of polyols to value added chemicals. Chinese Journal of Catalysis, 34, 492-507","Hendriks, A. T. W. M., & Zeeman, G. (2007). Pretreatments to enhance the digestability of ligneocellulosic materials. Bioresour. Technol., 100, 10-18.","Effendi, A., Gerhauser, H., & Bridgwater, A. V. (2008). Production of renewable phenolic resins by thermochemical conversion of biomass: a review. Renewable and sustainable energy reviews, 12, (8), 2092-2116. doi:10.1016/j.rser.2007.04.008","Verendel, J. J., Church, T. L., & Andersson, P. G. (2011). Catalytic One-Pot Production of Small Organics from Polysaccharides. Synthesis, (11), 1649-1677.","Zheng, M., Pang, J., Wang, A., & Zhang, T. (2014). One-pot catalytic conversion of cellulose to ethylene glycol and other chemicals: from fundamental discovery to potential commercialization. Chin. J. Catal. 35, 602-613. doi:org/ 10.1016/S1872-2067(14)60013-9","Xiao, Z. H., Jin, S. H., Pang, M., & Liang, C. H. (2013) Conversion of highly concentrated cellulose to 1,2-propanediol and ethylene glycol over highly efficient CuCr catalysts. Green Chem., V. 15. 891-895. doi:10.1039/C3GC40134K","Fuente-Hernandez, A., Corcos, P.-O., Beauchet, R., & Lavoie, J.-M. (March 20, 2013). Biofuels and Co-Products Out of Hemicelluloses. Chapter 1. Liquid, Gaseous and Solid Biofuels - Conversion Techniques. InTech. doi:10.5772/52645","Li, C., Zheng, M., Wang, A., Zhang, T. (2012). One-pot catalytic hydrocracking of raw woody biomass into chemicals over supported carbide catalysts: simultaneous conversion of cellulose, hemicellulose and lignin. Energy Environ. Sci., 5, 6383-6390. doi:10.1039/C1EE02684D","Terentieva, E. P., Udovenko, N. K., Pavlova, E. A., & Aliev, R. G. (2010). Fundamentals of chemistry of cellulose and wood: a teaching aid. St. Petersburg, SPbU RP, 23. (in Russian)."]} |
Databáze: | OpenAIRE |
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