Substituent-Dependent Azide Addition to Isocyanides Generates Strongly Luminescent Iridium Complexes

Autor: Chenggang Jiang, Louise M. Cañada, Ngoc Bao Nguyen, Michael D. S. Halamicek, Sami H. Nguyen, Thomas S. Teets
Rok vydání: 2023
Předmět:
Zdroj: Journal of the American Chemical Society. 145:1227-1235
ISSN: 1520-5126
0002-7863
DOI: 10.1021/jacs.2c11062
Popis: Ligand-centered functionalization reactions offer diverse strategies to prepare luminescent organometallic compounds. These compounds can have unique structures that are not accessible via traditional coordination chemistry and can possess enhanced or unusual photophysical properties. Here we show that bis-cyclometalated iridium bis-isocyanide complexes (
Databáze: OpenAIRE