Control of carbon nanotube morphology by change of applied bias field during growth

Autor: Prabhakar R. Bandaru, Chiara Daraio, Dong-Wook Kim, In Kyeong Yoo, Chong M. Wang, Joseph F. Aubuchon, Li-Han Chen, Andrew I. Gapin, Sungho Jin
Rok vydání: 2004
Předmět:
Zdroj: Applied Physics Letters. 85:5373-5375
ISSN: 1077-3118
0003-6951
DOI: 10.1063/1.1830081
Popis: Carbon nanotube morphology has been engineered via simple control of applied voltage during dc plasma chemical vapor deposition growth. Below a critical applied voltage, a nanotube configuration of vertically aligned tubes with a constant diameter is obtained. Above the critical voltage, a nanocone-type configuration is obtained. The strongly field-dependent transition in morphology is attributed primarily to the plasma etching and decrease in the size of nanotube-nucleating catalyst particles. A two-step control of applied voltage allows a creation of dual-structured nanotube morphology consisting of a broad base nanocone (~200 nm dia.) with a small diameter nanotube (~7 nm) vertically emanating from the apex of the nanocone, which may be useful for atomic force microscopy.
Databáze: OpenAIRE