Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis
| Autor: | Robert H. Morris, Alexandre A. Mikhailine, Alan J. Lough |
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| Rok vydání: | 2009 |
| Předmět: |
Models
Molecular Hydrogen Nitrogen Noyori asymmetric hydrogenation chemistry.chemical_element Stereoisomerism Crystallography X-Ray Ligands Transfer hydrogenation Biochemistry Catalysis Colloid and Surface Chemistry Organic chemistry Molecule Iron complex Molecular Structure Chemistry Phosphorus General Chemistry Ketones Template synthesis Combinatorial chemistry Iron Compounds |
| Zdroj: | Journal of the American Chemical Society. 131:1394-1395 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja809493h |
| Popis: | A distorted iron complex formed by template synthesis is the basis of a very efficient and economical catalyst system for the asymmetric transfer hydrogenation of ketones for the production of valuable enantioenriched alcohols. |
| Databáze: | OpenAIRE |
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