Fuel-Rich HCCI Engines as Chemical Reactors for Polygeneration: A Modeling and Experimental Study on Product Species and Thermodynamics

Autor: M. Werler, Ulrich Maas, Robert Hegner, Burak Atakan, Robert Schiessl
Rok vydání: 2017
Předmět:
Zdroj: Energy & Fuels. 31:14079-14088
ISSN: 1520-5029
0887-0624
Popis: The usage of a methane-fueled homogeneously charged compression ignition (HCCI) engine process for producing base chemicals like ethylene and synthesis gas together with some work output is investigated. This polygeneration process is studied by numerical modeling, accompanied by rapid compression machine experiments. Studies include the seeding of dimethyl ether (DME) as a reaction enhancer which allows methane conversion already at moderate, technically easily accessible compression ratios and precompression temperatures. The concept is promising for equivalence ratios above 2, predicting product gas mole fractions of up to 25 mol % H2, 20 mol % CO, and 2 mol % C2H4. These simulation results are largely consistent with the outcome of rapid compression machine (RCM) experiments, in which production of up to 20 mol % H2, 16 mol % CO, and 1 mol % C2H4 was detected. In addition to studying the product composition, thermodynamic aspects of the approach were investigated by comparing the exergetic efficiency ...
Databáze: OpenAIRE